P271 use only outdoors or in a wellventilated area. Material safety data sheet methanol 1 chemical product and company identification common name. Msds of methanol pdf msds of methanol pdf download. Chronic effects in serious cases absorption of methanol in the body may lead to damage to the eyesight. Toxic by inhalation, in contact w ith skin and if swallowed. Many reactions are conducted in liquids other than water. Gps safety summary methanol 10 july 2015 page 1 of 5 global product strategy gps safety summary. Do not allow contact with soil, surface or ground water. The severity of outcome following methanol ingestion may be more related to the time between ingestion and treatment, rather than the amount ingested. Like any other chemical, it should be treated with care, respect, and common sense. Substance name methanol casrn 67561 last revised 093020.
View product specific information, msds, references and buying faq. Anhydrous methanol is methanol that is free of water. Keep away from heat, hot surfaces, sparks, open flames and other. Methanol, when released into the air is expected to exist in the aerosol phase and will be degraded from the ambient atmosphere by the reaction with photochemically produced hydroxyl radicals with an estimated half life of 17. Dispose of waste in accordance with regional authority or local council bylaws. Methanol is hygroscopic, which means it absorbs moisture, including moisture from the air. Inhalation is the most common route of occupational exposure. A433s200 casno 67561 synonyms methyl alcohol recommended use laboratory chemicals. Methanol is also known as wood alcohol, because it was originally. Prevent entry into sewers, water courses, basements or confined areas. May cause adverse reproductive effects such as birth defects, miscarriages, or infertility based on animal data. After synthesis, methanol undergoes energyintegrated distillation to produce highpurity methanol e. Identification of the substancemixture and of the companyundertaking. The main benefit of methanol is that it is used in the creation of a large number of other chemicals.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wood alcohol, methyl alcohol, methyl hydroxide, methylol. If inhaled if breathed in, move person into fresh air. Metacresol mcresol, usp,ep msds quality excipients. Biodegrades easily in water methanol in fresh or salt water may have serious effects on aquatic life. In serious cases absorption of methanol in the body may lead to damage to the eyesight. Safety data sheet according to 29cfr19101200 and ghs rev. Ocular and neurological manifestationssharma et al.
Safety data sheet creation date 27apr2009 revision date 18jan2018 revision number 6 1. Identification of the substancemixture and of the companyundertaking 1. Methanol safety data sheet according to federal register vol. Material safety data sheet methanol and methanol, 50% vv. Methanol and methanol, 50% vv 6 osha highly hazardous. Acgih no component of this product present at levels greater than or equal to 0. Methanol, meets acs specifications, meets reagent specifications for testing uspnf monographs gr acs, 1. First aid measures for the full text of the hstatements mentioned in this section, see section 16.
Hazards identification emergency overview routes of entry for methanol are primarily absorption through the skin, eye contact, inhalation, or. Mixtures of methanol and water at concentrations greater than 20% methanol are still considered flammable. Tag solvent products mallet roadweg knights germiston 1401 republic of south africa tel. Accidental release measures stop leak if without risk. Dimethyl ether dme can play an important role in order to contain the rising imports and improve the energy security of india. Global product strategy gps safety summary methanol. Methanol 70% 67561 2006596 h225, h370 ghs02, ghs08 section 4 first aid measures 4. The halflife of methanol in surfact water ranges from 24 hrs. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Methanol is toxic and can very readily form extremely high vapor concentrations at room temperature. Options may include via sewerage treatment facility limitations on water.
A study on methanols toxic efffects on sewage sludge bacteria reported little effect on digestion at 0. Methanol in fresh or salt water may have serious effects on aquatic life. Houston, tx 77042 2500 city west boulevard, suite 650 u. Page 6 of 6 safety data sheet methanol recover and recycle e. Methanol is an essential ingredient in biofuels made with fats and oils, as it acts as a catalyst in the production of the biodiesel fuel. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Methanol microbial id chemicals 2 msds methanol inhalation. Methanol aegl technical support document pdf 107 pp, 361 k. The capacity of methanol plant has increased by 300 mtpd with addition of co2 in synthesis gas mixture as excess h2 is available for the methanol reaction. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness.
Acgih no component of this product present at levels greater than. Very toxic to aquatic life precautionary statements. If medical advice is needed, have product container or label at hand keep out of reach of children. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data. The low boilers are removed in the prerun column and the higher boiling. Methanol, ch3oh, is a clear and colorless liquid used in manufacturing a wide variety of chemical products, as a hydrogen carrier for fuel cell applications, and as an alternative fuel. It is degraded by reaction with photochemically produced hydroxyl radicals and has an. Methanol as an alternative transportation fuel in the u. The crude methanol is purified in a costsaving 2column or an energysaving 3column distillation unit.
Section 1 identification of the substancemixture and of. This gps safety summary s a highi level summary intended to provide the general public with an overview of product safety information on this chemical substance. Occupational exposure to methanol via inhalation is generally low but may be greater in less controlled conditions. If water is used for cooling, the solution will spread if not contained. Jul 22, 2014 methanol is an essential ingredient in biofuels made with fats and oils, as it acts as a catalyst in the production of the biodiesel fuel. Ntp no component of this product present at levels greater than or equal to 0. Twappm osha pel acgih tlv methanol 200 ppm 200 ppm water not established not established 3. Absorb with a noncombustible absorbent material such as sand or earth and containerize for disposal. Safety data sheet methanol page 2 affected skin with running water for 10 minutes or longer if substance is still on skin.
Contain and collect spillage with noncombustible, absorbent material e. Chemical product and company identification methanol. Based on its vapor pressure, methanol exists almost entirely in the vapor phase in the ambient atmosphere. At first, methanol causes cns depression with nausea, headache, vomiting, dizziness and incoordination. Msds, and expects the user to follow the precautions specified unless. You may need a pdf reader to view some of the files on this page. Download msds pdf search msds currently available for download bioworld offers methanol 50% for your research at low price.
Emergency overview appearance liquid colour colourless, clear odour. First aid measures general advice consult a physician. A study on methanols toxic effects on sewage sludge bacteria reported little effect on digestion at 0. The rfd is an estimate with uncertainty spanning perhaps an order of magnitude of a daily oral exposure to the human population including sensitive subgroups that is likely to be without an appreciable risk of deleterious effects during a lifetime. Transfer to hospital if there are burns or symptoms of poisoning. Safety data sheet product name synonyms product type emergency telephone number with hours of operation section 1. Pharmaceuticals and many other useful materials are made by reacting precursors in a process called chemical synthesis. Material safety data sheet instant fameinstant anaerobe. First aid measuresec if poisoning occurs, contact a doctor or poisons information centre. Methanol, also known as methyl alcohol amongst other names, is a chemical with the formula. If exposure limits have not been established, maintain airborne levels to an acceptable level. Org 500 mtpd of co2 is recovered from the flue gas using mhis proprietary ks1 solvent and injected in synthesis loop for boosting methanol production. Therefore, there is a need for rapid treatment of any ingestion exposure.
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